Triferrocenylphosphine oxide monohydrate.

نویسندگان

  • Alfred Muller
  • Gideon Steyl
  • Andreas Roodt
چکیده

The title compound, [Fe3(C5H5)3(C15H12OP)] H2O or Fc3PO H2O, was obtained as red crystals from the Friedel±Crafts alkylation reaction of PCl3 and ferrocene. Torsion angles (O PÐCÐFe/C) range fromÿ45.39 (9) toÿ56.11 (14) . The structure is stabilized by intermolecular hydrogen bonds [H O = 2.10 (3) and 2.00 (4) AÊ ], forming dimeric structures between pairs of O PFc3 and water molecules. A theoretical Tolman cone angle of 211 was calculated.

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عنوان ژورنال:
  • Acta crystallographica. Section C, Crystal structure communications

دوره 60 Pt 8  شماره 

صفحات  -

تاریخ انتشار 2004